Issue 6, 2023
From the journal:

Journal of Analytical Atomic Spectrometry

Experimental determination of ruthenium L-shell fluorescence yields and Coster–Kronig transition probabilities

Nils Wauschkuhn, ORCID logo *a   Katja Frenzel, ORCID logo a   Burkhard Beckhoffa  and  Philipp Hönicke ORCID logo a  

* Corresponding authors

a Physikalisch-Technische Bundesanstalt, Abbestr, 2-12, 10587 Berlin, Germany
E-mail: nils.wauschkuhn@ptb.de

Abstract

The L-shell fluorescence yields and the Coster–Kronig factors of ruthenium (and the corresponding uncertainty) were determined for the first time experimentally by applying radiometrically calibrated instrumentation of the Physikalisch-Technische Bundesanstalt. The resulting fluorescence yields (ωL3 = 0.0459(20), ωL2 = 0.0415(26), ωL1 = 0.0109(9)) and the Coster–Kronig factors (f23 = 0.177(32), f13 = 0.528(90), f12 = 0.173(73)) agree reasonable well with parts of the data from the literature.

Graphical abstract: Experimental determination of ruthenium L-shell fluorescence yields and Coster–Kronig transition probabilities

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Article information

DOI
https://doi.org/10.1039/D3JA00085K
Article type
Paper
Submitted
14 Mar 2023
Accepted
14 Apr 2023
First published
05 May 2023
This article is Open Access
Creative Commons BY-NC license

J. Anal. At. Spectrom., 2023,38, 1301-1306

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Experimental determination of ruthenium L-shell fluorescence yields and Coster–Kronig transition probabilities

N. Wauschkuhn, K. Frenzel, B. Beckhoff and P. Hönicke, J. Anal. At. Spectrom., 2023, 38, 1301 DOI: 10.1039/D3JA00085K

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